聚丙烯酸酯反相破乳剂制备条件优化及性能评价

以甲基丙烯酸(MAA)和丙烯酸乙酯(EA)为原料,通过乳液聚合制备了聚丙烯酸酯类反相破乳剂P(EA-MAA)。通过单因素实验考察了各因素对产物分子量、乳液粒径中值、聚合物凝胶残渣以及产物除油性能的影响,实验结果表明：在单体总质量分数为10%、单体配比(EA﹕MAA)为1:1,单体加入顺序为先EA后MAA,反应温度70℃,引发剂用量为1‰(占单体总质量分数),反应时间为6h的条件下,制备的P(EA-MAA)分子量大,粒径中值小,聚合物凝胶残渣少,除油率达到94.7%。     

逆电渗析反应器降解模拟甲基橙染料废水实验

利用逆电渗析（RED）技术可实现"废热治理废水"的目的.为探究RED反应器对染料废水的降解效果,构建了由40对膜构成的RED反应器.以NaCl水溶液作为工作溶液,甲基橙模拟废水作为降解对象,考察了废水流率、Cl^-浓度、Fe²⁺浓度、pH值、曝气流率和输出电流对模拟废水脱色率及COD去除率的影响.结果表明,对于RED反应器阳极回路印染废水,废水流率对其脱色率影响不大,但Cl^-浓度对其脱色率和COD去除率影响较大.对于RED反应器阴极回路印染废水,废水流率、Fe²⁺浓度、pH值和曝气流率均对其脱色率和COD去除率产生影响.当阳极回路废水氯盐浓度为0.5 mol·L^-1,阴极回路废水pH=2、Fe²⁺浓度为0.1 mmol·L^-1、曝气流率为600 mL·min^-1,两回路模拟废水流率均为82 mL·min^-1实验条件下,输出电流为0.25 A时,处理20 min后,阳/阴极回路模拟废水脱色率分别为99.9%和91.71%;处理80 min后,阳/阴极回路模拟废水COD去除率分别可达到52%和62%.     

微絮凝-微滤用于印染废水回用反渗透预处理的试验研究

采用微絮凝过滤-微滤作为反渗透的预处理工艺,用于印染废水二级生化出水回用深度处理.试验考察了预处理效果、工艺参数和反渗透系统运行情况,分析了膜污染的类型及特点.试验结果表明,微絮凝过滤-微滤作为反渗透的预处理工艺,系统运行稳定,相对于超滤-反渗透的"双膜法"工艺,投资和运行费用相对较低,有推广应用价值.     

反渗透处理糖厂二效汽凝水回用锅炉的研究

糖厂以二效汽凝水取代原水回用锅炉是"节能减排"的重要措施,但含糖量过高的二效汽凝水回用锅炉后,将影响锅炉高效、安全使用。故此采用一级反渗透装置对二效汽凝水进行除糖净化处理。实验结果表明:反渗透系统的脱盐率能够稳定在87.82%左右,出水水质完全达到中压锅炉补充给水水质标准。建议拥有中压锅炉的糖厂采用糖厂锅炉补充给水除糖净化新工艺。     

Forward osmosis coupled with lime-soda ash softening for volume minimization of reverse osmosis concentrate and CaCO3 recovery: A case study on the coal chemical industry

• Forward osmosis (FO) coupled with chemical softening for CCI ROC minimization • Effective removal of scale precursor ions by lime-soda ash softening • Enhanced water recovery from 54% to 86% by mitigation of FO membrane scaling • High-purity CaCO₃ was recovered from the softening sludge • Membrane cleaning efficiency of 88.5% was obtained by EDTA for softened ROC Reverse osmosis (RO) is frequently used for water reclamation from treated wastewater or desalination plants. The RO concentrate (ROC) produced from the coal chemical industry (CCI) generally contains refractory organic pollutants and extremely high-concentration inorganic salts with a dissolved solids content of more than 20 g/L contributed by inorganic ions, such as Na⁺, Ca²⁺, Mg²⁺, Cl⁻, and SO₄²⁻. To address this issue, in this study, we focused on coupling forward osmosis (FO) with chemical softening (FO-CS) for the volume minimization of CCI ROC and the recovery of valuable resources in the form of CaCO₃. In the case of the real raw CCI ROC, softening treatment by lime-soda ash was shown to effectively remove Ca²⁺/Ba²⁺ (>98.5%) and Mg²⁺/Sr²⁺/Si (>80%), as well as significantly mitigate membrane scaling during FO. The softened ROC and raw ROC corresponded to a maximum water recovery of 86% and 54%, respectively. During cyclic FO tests (4 × 10 h), a 27% decline in the water flux was observed for raw ROC, whereas only 4% was observed for softened ROC. The cleaning efficiency using EDTA was also found to be considerably higher for softened ROC (88.5%) than that for raw ROC (49.0%). In addition, CaCO₃ (92.2% purity) was recovered from the softening sludge with an average yield of 5.6 kg/m³ treated ROC. This study provides a proof-of-concept demonstration of the FO-CS coupling process for ROC volume minimization and valuable resources recovery, which makes the treatment of CCI ROC more efficient and more economical.     

纳滤处理炼化污水反渗透浓水

分别采用4种纳滤膜处理某炼化公司的反渗透浓水。在初始COD为57.8 mg/L、TOC为23.94 mg/L、ρ(Ca2+)为289.0 mg/L、ρ(Mg2+)为54.6 mg/L、ρ(SO42-)为327.7 mg/L、ρ(Cl-)为1 106.8 mg/L的条件下,经纳滤处理后COD去除率达60%以上,污水COD降至30 mg/L以下,TOC去除率为31.9%~85.5%,阳离子的去除率为33.9%~97.0%,SO42-的去除率为63.3%~97.6%,Cl-的去除率较低。膜A的膜孔分布密集,具有很高的通量,对有机物和无机盐的截留效果较差;膜B和膜C对有机物和二价离子的截留效果较好;膜D的膜孔分布稀松,膜通量最低,对有机物和无机盐的截留能力均较强,但随出水体积的增加,对无机盐的截留能力下降较为明显。4种纳滤膜的性能各异,可满足不同企业的需求,具有良好的应用前景。     

印染废水回用处理的设计实例

采用"厌氧水解—缺氧—好氧—二次沉淀—超滤—反渗透"组合工艺进行印染废水的处理回用。运行结果表明,在平均进水COD和色度分别为508 mg/L和1695倍的情况下,COD和色度的总去除率分别为94.2%和98.8%,硬度不超过10 mg/L,铁、锰离子未检出,各项指标均达到HJ 471—2009《纺织染整工业废水治理工程技术规范》中的回用标准。GC-MS分析结果显示,二沉池出水中主要有机物成分复杂,超滤出水中有机物浓度有一定降低,反渗透出水中酸类全部被去除、苯胺类和烷烃类含量明显降低。从染色的白位沾色、手感、颜色和亮度等指标分析,回用水的染色效果远优于工业水。污水处理工程总投资约1×10~7元,设计规模4 500 m~3/d,回用水规模2 500 m~3/d,回用率55%,回用运行成本1.80元/m~3。     

A new type of refrigerator and its cycle

The world is facing an energy and climate crisis. Globally, the energy sector emits 26 billion tonnes of CO₂ each year, and electricity production alone accounts for 41% of emissions (European Wind Energy Association. 2008. Pure Power: Wind Energy Scenarios up to 2030. European Wind Energy Association. p. 6). Currently, reducing CO₂ emissions and curbing climate change have become global priorities, and we only have a narrow window of time left in which to act. The new type of refrigerator can offer an immediate and concrete solution to the many energy and climate challenges that we are facing. This is an account of a new type of refrigerator and its cycle for use in the refrigeration industry. For its cycle, the working substance is air or other gases; its cycle is very similar to that of the reverse Brayton cycle (Hou, Y., Zhao, H. L., Chen, C. Z., and Xiong, L. Y. 2006. “Developments in Reverse Brayton Cycle Cryocooler in China.” Cryogenics 46 (5): 403–407). In the cycle of the new type of refrigerator, the isochoric exothermic process and the isothermal exothermic compression process replace the isobaric exothermic compression process of the reverse Brayton cycle. The new type of refrigerator can produce a net electrical energy, and it is not a perpetual motion machine, because the environmental enthalpy and atmospheric pressure can be utilized as the external energy sources, which cannot be performed by any other conventional refrigerators; therefore, the reliability and significance of this new type of refrigerator is self-evident.     

UF-RO-NF应用于电镀镍漂洗废水回用中试研究

采用“UF-RO-NF”中试装置处理电镀镍漂洗废水,在周期运行的工况下,考察其浓淡水回用效果以及膜通量变化情况。研究表明,该套系统淡水COD、Ni离子、电导率的平均值为70.6 mg/L、2.93 mg/L、91.1μs/cm^2,远低于该生产车间镀镍漂洗水,可以回用。浓水COD、Ni离子、电导率相对于漂洗水均有4倍以上的浓缩效果,具有一定的回用价值。整个系统在试验运行10个周期内膜通量保持不变。     

再生资源供应链的结构、行为和绩效分析

再生资源是一种特殊的资源类型,兼具资源资产产权和环境产权,两者相互作用引导其开发利用自组织形成了正规与非正规回收利用者相互交织的完整逆向供应链系统。协调其中各主体间的利益关系、减少逆向供应链的环境污染和整体运行损耗是再生资源开发利用水平提升的关键手段。为此,本文以北京市废旧电视为例,利用实地调研的方法,系统分析了再生资源供应链的结构、行为和绩效(SCP)。结果表明:(1)消费者选择一级回收者时具有价值性、便捷性和规范性三种偏好。销售商回收模式可较好地满足消费者的需求,成为其首选方案,然而,"以旧换新"限制了无需购买新电视的人群。游商以45%的份额占据了剩余一级回收市场的主导地位。(2)一级与二级回收者间形成了稳定的合作关系,二手市场扩大了一级回收者的利润,中间商则为一级回收者提供了稳定的需求保障。(3)受到非正规拆解作坊的挤占,正规拆解企业产能严重过剩。一方面,降低了拆解企业对收购产品的质量要求,致使中间商偷换有价组件和跨境转移电子废弃物等问题日益严重。另一方面,正规拆解企业会提高收购价格,致使政府补贴的基金大部分转移至回收环节,巩固了现有的正规与非正规回收者共存的供应链结构。(4)个体中间商及非正规拆解利用作坊是再生资源供应链低效率的关键。本文调整了现有的家电基金制度,建议在电视销售环节向消费者征收40元/台的基金,并将其中的10元/台用于扶持政府可管控的正规主体中间商,代替个体中间商的功能,其余金额可用于弥补现有基金的亏空。该种模式可充分利用现有的一级回收者及二手市场,并可有效提升再生资源供应链的整体绩效水平。